Material Safety Data Sheet
3-Dimethylamino Acrolein
Section 1 - Chemical Product and Company Identification
MSDS Name: 3-Dimethylamino Acrolein
Catalog Numbers: 86-40953

Section 2 - Composition, Information on Ingredients 
CAS# 927-63-9
Chemical Name: 3-Dimethylamino Acrolein
Percent  98.0%
EINECS/ELINCS:213-157-7
Hazard Symbols:C
Risk Phrases:34

Section 3 - Hazards Identification 
EMERGENCY OVERVIEW
According to Regulation (EC) No1272/2008: Skin corrosion
According to European Directive 67/548/EEC as amended.: Causes burns.

Potential Health Effects
Inhalation: May be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract.
Ingestion: May be harmful if swallowed. Causes burns.
Skin: May be harmful if absorbed through skin. Causes skin burns.
Eyes: Causes eye burns.

Section 4 - First Aid Measures
General advice: Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled: If breathed in, move person into fresh air. If not breathing give artificial respiration Consult a physician.
In case of skin contact: Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a physician.
In case of eye contact: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Section 5 - Fire Fighting Measures 
Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special protective equipment for fire-fighters: Wear self contained breathing apparatus for fire fighting if necessary.

Section 6 - Accidental Release Measures 
Personal precautions: Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas.
Environmental precautions: Do not let product enter drains.
Methods and materials for containment and cleaning up: Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal.

Section 7 - Handling and Storage 
Precautions for safe handling: Avoid inhalation of vapour or mist; Normal measures for preventive fire protection.
Conditions for safe storage: Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.

Section 8 - Exposure Controls, Personal Protection 
Engineering Controls: Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.

Personal Protective Equipment
Eyes: Tightly fitting safety goggles. Faceshield (8-inch minimum).
Hand protection: The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Handle with gloves.
Skin and body protection: Choose body protection according to the amount and concentration of the dangerous substance at the work place.
Respirators: Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Section 9 - Physical and Chemical Properties 
Physical State: Liquid
Color: Brown
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point:: 270-273 °C(lit.)
Melting point: Not available.
Autoignition Temperature: Not available
Flash Point: 113 °C - closed cup
Explosion Limits: Lower: Not available
Explosion Limits: Upper: Not available
Decomposition Temperature:Not available.
Solubility:  Not available.
Specific Gravity/Density: 0.99 g/mL at 25 °C(lit.)
Molecular Formula: C5H9NO
Molecular Weight:: 99.13

Section 10 - Stability and Reactivity 
Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid:no data available
Incompatibilities with Other Materials: Strong oxidizing agents
Hazardous Decomposition Products: Hazardous decomposition products formed under fire conditions. - Carbon oxides, nitrogen oxides (NOx).
Hazardous Polymerization:Has not been reported.

Section 11 - Toxicological Information
RTECS#: CAS# 927-63-9: None listed     
LD50/LC50: RTECS: Not available.
Carcinogenicity:
 No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Other Studies: The toxicological properties have not been fully investigated.

Signs and Symptoms of Exposure
Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea, Vomiting, To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Additional Information: RTECS: Not available

Section 12 - Ecological Information 
Nor available

Section 13 - Disposal Considerations 
Product: Observe all federal, state, and local environmental regulations. Contact a licensed professional waste
disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn
in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging: Dispose of as unused product.

Section 14 - Transport Information 
ADR/RID
UN-Number: 3267 Class: 8 Packing group: II
Proper shipping name: CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (3-Dimethylamino Acrolein)
IMDG
UN-Number: 3267 Class: 8 Packing group: II EMS-No: F-A, S-B
Proper shipping name: CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (3-Dimethylamino Acrolein)
Marine pollutant: No
IATA
UN-Number: 3267 Class: 8 Packing group: II
Proper shipping name: Corrosive liquid, basic, organic, n.o.s. (3-Dimethylamino Acrolein)

Section 15 - Regulatory Information 
European/International Regulations
      European Labeling in Accordance with EC Directives
           Hazard Symbols: C
           Risk Phrases:
                   R 34 Causes burns
           Safety Phrases:
                   S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
                   S 36/37/39 Wear suitable protective clothing ,Wear suitable gloves,Wear eye/face protection
                   S 45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
           WGK (Water Danger/Protection)
                   CAS# 927-63-9: Not available
           Canada
                   CAS# 927-63-9 is listed on Canada's NDSL List
US Federal
           TSCA
                   CAS# 927-63-9 is listed on the TSCA Inventory.

 Section 16 - Additional Information
Text of H-code(s) and R-phrase(s) mentioned in Section 3

While the information herein is believed to be reliable, it is furnished without warranty of any kind. It shall be used only as a guide. We assume no liabilities from the use of this product or information contained herein.